Evaluation of the quality indicators of food-grade glycerin derived from different oil/fat raw materials

Authors

  • Mikhailo Mushtruk National University of Life and Environmental Sciences of Ukraine, Faculty of Food Technology and Quality Control of Agricultural Products, Department of Processes and Equipment for Processing of Agricultural Production, Heroes of Defense Str., 12 B, 03040, Kyiv, Ukraine, Tel.: +380989412606 , National University of Life and Environmental Sciences of Ukraine image/svg+xml Author
  • Volodymyr Vasyliv National University of Life and Environmental Sciences of Ukraine, Faculty of Food Technology and Quality Control of Agricultural Products, Department of Processes and Equipment for Processing of Agricultural Production, Heroes of Defense Str., 12 B, 03040, Kyiv, Ukraine , National University of Life and Environmental Sciences of Ukraine image/svg+xml Author
  • Vitalii Hidzhelitskyi Kyiv Cooperative Institute of Business and Law, Department of Food Technology, Y. Zdanovska Str., 18, 03022, Kyiv, Ukraine Author
  • Roman Mukoid National University of Food Technology, Institute of Food Technology, Department of biotechnology of fermentation and winemaking products, Volodymyrska Str. 68, 01601, Kyiv, Ukrain , National University of Food Technologies image/svg+xml Author
  • Svitlana Savchuk National University of Life and Environmental Sciences of Ukraine, Education and research institute of Energetics, Automatics and Energy saving, Department of Higher and Applied Mathematics, Heroes of Defense Str., 12 B, 03040, Kyiv, Ukraine , National University of Life and Environmental Sciences of Ukraine image/svg+xml Author
  • Inna Popova National University of Food Technology, Institute of Food Technology, Department of Food Chemistry, Volodymyrska Str. 68, 01601, Kyiv, Ukraine , National University of Food Technologies image/svg+xml Author
  • Serhii Khalin Eastern Ukrainian National University named after Volodymyr Dahl., Faculty of Agriculture, Department of Agronomy and Land Management, John Paul II St., 17, 01042, Kyiv, Ukraine Author
  • Serhii Mykhniuk National University of Life and Environmental Sciences of Ukraine, Faculty of Humanities and Pedagogy, Department of Management and Educational Technologies, Heroes of Defense Str., 15, 03040, Kyiv, Ukraine , National University of Life and Environmental Sciences of Ukraine image/svg+xml Author

DOI:

https://doi.org/10.5219/scifood.120

Keywords:

food-grade glycerin, quality, raw materials, regulatory characteristics, planar geometric models, factor space, evaluation criteria

Abstract

The relevance of the research is determined by the growing demand for food-grade glycerin and the need for an objective, comprehensive assessment of its quality. In modern domestic and global food technologies, glycerin-containing products are characterized by a wide range of functional properties: it is used as a sweetener in confectionery, an emulsifier to prevent the stratification of fat systems, a solvent for uniform distribution of biologically active components, as well as as a safe additive in the production of beverages, alcoholic beverages, pasta and dried fruits. The combination of these properties gives glycerin a significant place not only in the European but also in the global market for the food and processing industry. In this regard, the priority research area is the improvement of approaches to assessing product quality by comprehensively analyzing its properties. The purpose of this study is to determine the quality of glycerin-containing products obtained from oil and fat raw materials using the developed mathematical models of polygons for numerical analysis. The assessment was carried out using a set of indicators, including color, relative density, density at 20 °C, reaction to an alkaline medium, mass fractions of glycerin and ash, and the saponification coefficient. This enabled the formation of dimensionless complexes and the numerical analysis of the compliance of the studied samples with regulatory requirements. Experimental data processing and the calculation of quality criteria were performed using programming methods and the Excel environment, enabling us to develop geometric quality models and determine the required parameters for calculations. According to the studies, samples obtained from technical animal fats and rapeseed oil do not meet regulatory requirements, exceeding the average quality indicators by more than 3.5 times. Instead, the best characteristics were demonstrated by samples of sunflower and soybean oil, which correspond to the maximum regulatory values, while the average indicators exceeded the regulatory values by 14% to 24%. The proposed mathematical models can be effectively used to assess the condition of objects of varying complexity, provided that a wide range of physical, mechanical, chemical, and biological characteristics is considered, thereby ensuring the objectivity and scientific validity of the results.

References

1. Lima, P. J. M., da Silva, R. M., Neto, C. A. C. G., Gomes e Silva, N. C., Souza, J. E. da S., Nunes, Y. L., & Sousa dos Santos, J. C. (2021). An overview on the conversion of glycerol to value‐added industrial products via chemical and biochemical routes. Biotechnology and Applied Biochemistry, 69(6), 2794–2818. https://doi.org/10.1002/bab.2098 DOI: https://doi.org/10.1002/bab.2098

2. Mushtruk, М. М., Chuiuk, R. V., Mushtruk, N. M., Vasyliv, V. P., Slobodyanyuk, N. M., Rudyk, Y. M., & Gruntovskyi, M. S. (2025). Raw material base for the production of food and pharmacological glycerin. Regulatory Mechanisms in Biosystems, 16(2), e25057. https://doi.org/10.15421/0225057 DOI: https://doi.org/10.15421/0225057

3. Becker, L. C., Bergfeld, W. F., Belsito, D. V., Hill, R. A., Klaassen, C. D., Liebler, D. C., Marks, J. G., Jr, Shank, R. C., Slaga, T. J., Snyder, P. W., Gill, L. J., & Heldreth, B. (2019). Safety Assessment of Glycerin as Used in Cosmetics. International Journal of Toxicology, 38(3_suppl), 6S-22S. https://doi.org/10.1177/1091581819883820 DOI: https://doi.org/10.1177/1091581819883820

4. Hammoudeh, A. Y., Obeidat, S. M., Abboushi, E. Kh., & Mahmoud, A. M. (2020). FT-IR Spectroscopy for the Detection of Diethylene Glycol (DEG) Contaminant in Glycerin-Based Pharmaceutical Products and Food Supplements. Acta Chimica Slovenica, 67(2), 530–536. https://doi.org/10.17344/acsi.2019.5553 DOI: https://doi.org/10.17344/acsi.2019.5553

5. Shanina, O., Minchenko, S., Gavrysh, T., Sukhenko, Y., Sukhenko, V., Vasyliv, V., Miedviedieva, N., Mushtruk, M., Stechyshyn, M., & Rozbytska, T. (2020). Substantiation of basic stages of gluten-free steamed bread production and its influence on quality of finished product. Potravinarstvo Slovak Journal of Food Sciences, 14, 189–201. https://doi.org/10.5219/1200 DOI: https://doi.org/10.5219/1200

6. Freire, L. F. da S., Cruz, G. R. B., Costa, R. G., Ribeiro, N. L., Guerra, R. R., Sousa, S., Lima, A. M. de, Silva, G. F., Sant’ana, A. M. da S., & Nascimento, G. V. do. (2022). Glycerin diet affects the size of the fat globule and the fatty acid profile of goat’s milk. Food Science and Technology, 42. https://doi.org/10.1590/fst.85821 DOI: https://doi.org/10.1590/fst.85821

7. Mushtruk, N. (2025). Comparative analysis of pectin-containing paste properties using artificial intelligence. Human and Nation’s Health, 3(3), 63–79. https://doi.org/10.31548/humanhealth.3.2025.63 DOI: https://doi.org/10.31548/humanhealth.3.2025.63

8. Bezerra, H. F. C., Santos, E. M., de Carvalho, G. G. P., de Oliveira, J. S., de Moura Zanine, A., Pinho, R. M. A., de Araújo, M. L. G. M. L., Perazzo, A. F., & Ferreira, D. de J. (2022). Effect of crude glycerin levels on meat quality and carcass characteristics of crossbred Boer goats. Food Science & Nutrition, 10(7), 2312–2317. https://doi.org/10.1002/fsn3.2839 DOI: https://doi.org/10.1002/fsn3.2839

9. Gomes, R. N., De Paula, T. A., De Carvalho, F. F. R., Ferreira, M. A., Barreto, L. M. G., Neves, M. L. M. W., De Oliveira, A. B., Mendes, G. O., Cordeiro, E. H. A., & Véras, A. S. C. (2022). Carcass characteristics and meat quality of goats fed increasing levels of crude glycerin. Anais Da Academia Brasileira de Ciências, 94(1). https://doi.org/10.1590/0001-3765202220200083 DOI: https://doi.org/10.1590/0001-3765202220200083

10. Alang, M. B., Kor, N. M., & Ndifon, P. T. (2022). Synthesis and Characterization of Bio-Glycerol from Cameroon Palm Kernel Seed Oil. Green and Sustainable Chemistry, 12(02), 28–40. https://doi.org/10.4236/gsc.2022.122003 DOI: https://doi.org/10.4236/gsc.2022.122003

11. Mushtruk, M., Sukhenko, V., Vasyliv, V., Harmatovskyi, Y., & Chuiuk, R. (2026). Energy-efficient solutions in the production of diesel biofuel from vegetable oils. In Lecture Notes in Mechanical Engineering (pp. 676–689). Springer Nature Switzerland. https://doi.org/10.1007/978-3-032-14926-8_55 DOI: https://doi.org/10.1007/978-3-032-14926-8_55

12. Abbas Fadhil Khalaf, Farhan Lafta Rashid, Hayder I. Mohammed, Ali Basem, Hussein Rasool Abid, & Mudhar A. Al-Obaidi. (2024). Numerical Unveiling the Dynamics of Glycerin-Water Mixing: Insights into Compatibility and Behavior. Journal of Advanced Research in Numerical Heat Transfer, 16(1), 35–56. https://doi.org/10.37934/arnht.16.1.3556 DOI: https://doi.org/10.37934/arnht.16.1.3556

13. DSTU 4553:2006. (2006). Glycerin. Specifications. Kyiv, Ukraine: State Committee for Technical Regulation and Consumer Policy of Ukraine.

14. International Organization for Standardization. (1988). ISO 760: Determination of water – Karl Fischer method. Geneva, Switzerland.

15. International Organization for Standardization. (2011). ISO 12185: Crude petroleum and petroleum products – Determination of density – Oscillating U-tube method. Geneva, Switzerland.

16. International Organization for Standardization. (2018). ISO 3104: Petroleum products – Determination of kinematic viscosity. Geneva, Switzerland.

17. International Organization for Standardization. (2008). ISO 10523: Water quality – Determination of pH. Geneva, Switzerland.

18. European Directorate for the Quality of Medicines. (2023). European Pharmacopeia (11th ed.). Strasbourg: EDQM.

19. United States Pharmacopeia. (2022). USP–NF: Glycerin monograph. Rockville, MD.

20. International Organization for Standardization. (2020). ISO 660: Animal and vegetable fats and oils – Determination of acid value and acidity. Geneva, Switzerland.

21. International Organization for Standardization. (2017). ISO 6271: Clear liquids – Estimation of colour by the platinum-cobalt scale. Geneva, Switzerland.

22. Palamarchuk, I., Mushtruk, M., Piddubny, V., Osokina, N., Chahaida, A., Mihailik, V., Herasymchuk, O., & Tkachenko, H. (2025). Modeling of the qualitative state of oilseeds from soybean seeds by multifactorial analysis of factor areas. Scifood, 19, 61–78. https://doi.org/10.5219/scifood.5 DOI: https://doi.org/10.5219/scifood.5

23. Palamarchuk, I., Mushtruk, M., Vasyliv, V., Stefan, E., Priss, O., Babych, I., Karpovych, I., & Pushanko, N. (2024). Modelling the centrifugal mixing process of minced meat to optimise the production of chopped meat semi-finished products. Potravinarstvo Slovak Journal of Food Sciences, 18, 297–312. https://doi.org/10.5219/1959 DOI: https://doi.org/10.5219/1959

24. Palamarchuk, I., Yuanxia, F., Hudzenko, M., & Palamarchuk, P. (2025). Mathematical analysis of Chinese sausages for the content of harmful substances. Human and Nation’s Health, 3(3), 34–48. https://doi.org/10.31548/humanhealth.3.2025.34 DOI: https://doi.org/10.31548/humanhealth.3.2025.34

25. Bal-Prylypko, L., Nikolaenko, M., Mushtruk, M., Nazarenko, M., & Beiko, L. (2024). Physical and mathematical modelling of the process of cooking minced meat with spelt flour and champignon mushrooms. Animal Science and Food Technology, 15(2), 38–55. https://doi.org/10.31548/animal.2.2024.38 DOI: https://doi.org/10.31548/animal.2.2024.38

26. Palamarchuk, I. P., Mushtruk, M. M., Palamarchuk, V. I., Deviatko, O. S., Wójcik, W., Kalizhanova, A., & Kozbakova, A. (2021). Physical-mathematical modelling of the process of infrared drying of rape with vibration transport of products. In Mechatronic Systems 1 (pp. 243–253). Routledge. https://doi.org/10.1201/9781003224136-21 DOI: https://doi.org/10.1201/9781003224136-21

27. Johnson, D. T., & Taconi, K. A. (2020). The glycerin glut: Options for the value-added conversion of crude glycerol resulting from biodiesel production. Environmental Progress & Sustainable Energy, 39(1), e13334. https://doi.org/10.1002/ep.13334 DOI: https://doi.org/10.1002/ep.13334

28. Tan, H. W., Abdul Aziz, A. R., & Aroua, M. K. (2013). Glycerol production and its applications as a raw material: A review. Renewable and Sustainable Energy Reviews, 27, 118–127. https://doi.org/10.1016/j.rser.2013.06.035 DOI: https://doi.org/10.1016/j.rser.2013.06.035

29. Ayoub, M., & Abdullah, A. Z. (2020). Critical review of the current scenario and significance of crude glycerol resulting from the biodiesel industry towards a more sustainable renewable energy industry. Renewable and Sustainable Energy Reviews, 16(5), 2671–2686. https://doi.org/10.1016/j.rser.2012.01.054 DOI: https://doi.org/10.1016/j.rser.2012.01.054

30. Yang, F., Hanna, M. A., & Sun, R. (2020). Value-added uses for crude glycerol. Biotechnology for Biofuels, 5, 13. https://doi.org/10.1186/1754-6834-5-13 DOI: https://doi.org/10.1186/1754-6834-5-13

31. Quispe, C. A. G., Coronado, C. J. R., & Carvalho, J. A. (2020). Glycerol: Production, consumption, prices, characterization and new trends in combustion. Renewable and Sustainable Energy Reviews, 27, 475–493. https://doi.org/10.1016/j.rser.2013.06.017 DOI: https://doi.org/10.1016/j.rser.2013.06.017

32. Thompson, J. C., & He, B. B. (2020). Characterization of crude glycerol from biodiesel production. Applied Engineering in Agriculture, 22(2), 261–265. https://doi.org/10.13031/2013.20272 DOI: https://doi.org/10.13031/2013.20272

33. da Silva, G. P., Mack, M., & Contiero, J. (2020). Glycerol: A promising and abundant carbon source for industrial microbiology. Biotechnology Advances, 27(1), 30–39. https://doi.org/10.1016/j.biotechadv.2008.07.006 DOI: https://doi.org/10.1016/j.biotechadv.2008.07.006

34. Pachauri, N., & He, B. (2020). Value-added utilization of crude glycerol from biodiesel production: A survey of current research activities. International Journal of Chemical Engineering, 2012, 1–17. https://doi.org/10.1155/2012/946497

35. Awogbemi, O., & Desai, D. A. (2025). Recent advances in purification technologies for biodiesel-derived crude glycerol. International Journal of Ambient Energy, 46(1). https://doi.org/10.1080/01430750.2025.2533373 DOI: https://doi.org/10.1080/01430750.2025.2533373

36. Bansod, Y., Crabbe, B., Forster, L., Ghasemzadeh, K., & D’Agostino, C. (2024). Evaluating the environmental impact of crude glycerol purification derived from biodiesel production: A comparative life cycle assessment study. Journal of Cleaner Production, 437, 140485. https://doi.org/10.1016/j.jclepro.2023.140485 DOI: https://doi.org/10.1016/j.jclepro.2023.140485

37. Shevchenko, L. V., Dovbnia, Y. Y., Permyakova, N. М., Zheltonozhskaya, Т. B., Shulyak, S. V., & Klymchuk, D. O. (2022). Influence of nanosilver in hybrid carriers on morphological and biochemical blood parameters of laying hens. Regulatory Mechanisms in Biosystems, 13(1), 15–22. https://doi.org/10.15421/022203 DOI: https://doi.org/10.15421/022203

38. Jiang, H., Geng, K., Zhang, L., & Wang, L. (2025). Simulation and optimization of crude glycerol refining process as a co-product of biodiesel. Separation and Purification Technology, 353, 128567. https://doi.org/10.1016/j.seppur.2024.128567 DOI: https://doi.org/10.1016/j.seppur.2024.128567

39. Qian, S., Liu, X., Turner, C. H., & Bara, J. E. (2021). Glycerol‐derived solvents containing two or three distinct functional groups enabled by trifluoroethyl glycidyl ether. AIChE Journal, 68(3). https://doi.org/10.1002/aic.17533 DOI: https://doi.org/10.1002/aic.17533

40. Li, B., Li, J., Ren, S., Gu, S., Liu, Z., & Liu, L. (2025). Development of advanced mathematical modeling for capillary bundle evaporation of 1,2-propylene glycol–glycerin mixtures in porous media. Chinese Journal of Chemical Engineering, 80, 261–273. https://doi.org/10.1016/j.cjche.2024.11.012 DOI: https://doi.org/10.1016/j.cjche.2024.11.012

41. Feitosa, F. L., de Sousa Costa Filho, J., de Sousa, C. D., Martins, W. S., Barbosa, M. T. G., Cavallini, G. S., de Oliveira, L. F. C., de Souza, N. L. G. D. (2022). Crude glycerin, a by-product of biodiesel, can be used as an admixture for concrete pieces. Iranian Journal of Science and Technology, Transactions of Civil Engineering, 47(2), 863–872. https://doi.org/10.1007/s40996-022-00953-3 DOI: https://doi.org/10.1007/s40996-022-00953-3

42. Costa, A., de Oliveira, A., Esposito, R., Len, C., Luque, R., Noronha, R., Rocha Filho, G., & Nascimento, L. (2022). Glycerol and Catalysis by Waste/Low-Cost Materials – A Review. Catalysts, 12(5), 570. https://doi.org/10.3390/catal12050570 DOI: https://doi.org/10.3390/catal12050570

43. Palamarchuk, I., Mushtruk, M., Lypovy, I., Petrychenko, I., & Vlasenko, I. (2022). Justification of Vibroventrentic External Load During Mechanical Pressing of Glycerin-Containing Products. In Lecture Notes in Mechanical Engineering (pp. 208–217). Springer International Publishing. https://doi.org/10.1007/978-3-031-06044-1_20 DOI: https://doi.org/10.1007/978-3-031-06044-1_20

44. Clomburg, J. M., & Gonzalez, R. (2013). Anaerobic fermentation of glycerol: A platform for renewable fuels and chemicals. Trends in Biotechnology, 31(1), 20–28. https://doi.org/10.1016/j.tibtech.2012.10.006 DOI: https://doi.org/10.1016/j.tibtech.2012.10.006

45. Mushtruk, M., Mushtruk, N., Slobodyanyuk, N., Vasyliv, V., & Zheplinska, M. (2024). Enhanced energy independence: converting animal fat into biodiesel. International Journal of Environmental Studies, 81(1), 134–144. https://doi.org/10.1080/00207233.2024.2314860 DOI: https://doi.org/10.1080/00207233.2024.2314860

46. Maquirriain, M. A., Neyertz, C. A., Querini, C. A., & Pisarello, M. L. (2021). Crude glycerine purification by solvent extraction. Brazilian Journal of Chemical Engineering, 39(1), 235–249. https://doi.org/10.1007/s43153-021-00164-9 DOI: https://doi.org/10.1007/s43153-021-00164-9

47. Dhabhai, R., Koranian, P., Huang, Q., Scheibelhoffer, D. S. B., & Dalai, A. K. (2023). Purification of glycerol and its conversion to value-added chemicals: A review. Separation Science and Technology, 58(7), 1383–1402. https://doi.org/10.1080/01496395.2023.2189054 DOI: https://doi.org/10.1080/01496395.2023.2189054

48. Chuaypat, C., Bardeeniz, S., Hussain, M. A., & Panjapornpon, C. (2026). Energy structure analysis of the process heating system in crude glycerin refinery using a physics-guided dual-region echo state network for multirate steam modeling. Applied Thermal Engineering, 286, 129365. https://doi.org/10.1016/j.applthermaleng.2025.129365 DOI: https://doi.org/10.1016/j.applthermaleng.2025.129365

49. Silva, S. S. O., Nascimento, M. R., Lima, R. J. P., Luna, F. M. T., & Cavalcante Júnior, C. L. (2023). Experimental and Simulation Studies for Purification and Etherification of Glycerol from the Biodiesel Industry. AppliedChem, 3(4), 492–508. https://doi.org/10.3390/appliedchem3040031 DOI: https://doi.org/10.3390/appliedchem3040031

50. Rathee, M., Chahal, S., Jain, P., Divakar, S., Singh, S., & Tomar, S. S. (2022). Prosthetic management of resorbed ridges through fabrication of hollow denture using three-dimensional glycerin spacer and neutral zone technique. Saudi Journal of Oral Sciences, 9(3), 198–201. https://doi.org/10.4103/sjoralsci.sjoralsci_46_22 DOI: https://doi.org/10.4103/sjoralsci.sjoralsci_46_22

51. Aslan, V. (2024). The analysis of classical, polynomial regression, and cubic spline mathematical models in hemp biodiesel optimization: an experimental comparison. Environmental Science and Pollution Research, 31(6), 9392–9407. https://doi.org/10.1007/s11356-023-31720-0 DOI: https://doi.org/10.1007/s11356-023-31720-0

52. Maya-Rodriguez, M. C., Carvajal-Mariscal, I., López-Muñoz, R., Lopez-Pacheco, M. A., & Tolentino-Eslava, R. (2025). Computer Science Techniques Applied to Temperature Control in Biodiesel Production: Mathematical Modeling, Optimization, and Sensorless Technique. Processes, 13(3), 672. https://doi.org/10.3390/pr13030672 DOI: https://doi.org/10.3390/pr13030672

Downloads

Published

2026-04-17

How to Cite

Evaluation of the quality indicators of food-grade glycerin derived from different oil/fat raw materials. (2026). Scifood, 20, 318-335. https://doi.org/10.5219/scifood.120

Most read articles by the same author(s)

Similar Articles

11-20 of 58

You may also start an advanced similarity search for this article.